📝 SummarXiv

Abstract

Prestellar cores represent the initial conditions of star formation, but heavy molecules such as CO are strongly depleted in their cold, dense interiors, limiting the ability to probe core centers. Deuterated molecular ions therefore emerge as key tracers because deuterium fractionation is enhanced at low temperatures. We present the first direct observation of ortho-H2D+ depletion in the prestellar core G205.46-14.56M3 using ALMA 820um continuum and ortho-H2D+(110-111) data at ~300-au resolution. We confirm the previously reported two substructures, B1 and B2, and identify a central ortho-H2D+ depletion zone toward B1 with ~6$\sigma$ contrast and an inferred diameter $\lesssim$600au, together with a peak $x$(N2D+)/$x$(N2H+)=$1.03^{+0.07}_{-0.56}$. The observationally inferred profiles of $x$(ortho-H2D+) and $x$(N2D+)/$x$(N2H+) are reproduced by a deuteration-focused chemo-dynamical model; however, the central ortho-H2D+ depletion is only marginally matched within the $2\sigma$ upper limit, likely suggesting additional deuteration in the depletion zone. From these models we infer a core age of ~0.42Ma, comparable to the free-fall time, suggesting that the substructures formed via rapid, turbulence-dominated fragmentation rather than slow, quasi-static contraction. Our observations also reveal that ortho-H2D+ velocity dispersions are largely subsonic in the core and nearly thermal between B1 and B2, consistent with turbulence dissipating within a few free-fall times. These results highlight the critical role of deuterated ions for both chemical evolution and dynamics in dense cores.