Short-wavelength mesophases in the ground states of core-softened particles in two-dimensions

Rômulo Cenci, Lucas Nicolao, Alejandro Mendoza-Coto

公開日: 2025/7/9

Abstract

We describe the formation of short-wavelength mesophases in a two-dimensional core-softened particle system. By proposing a series of specific ansatz for each relevant phase, we performed a variational analysis to obtain the ground-state phase diagram. Our results reveal a variety of cluster lattice phases with distinct cluster orientations, alongside traditional two-dimensional Bravais lattices such as square, triangular, oblique, and rectangular structures, as well as other non-Bravais arrangements including honeycomb and kagome phases. We characterize in detail the ground-state phase transitions and identify coexistence regions between competing phases, capturing both first-order and continuous transitions. In addition, we highlight the crucial role of the competing length scales introduced by the hard-core repulsion in shaping the rich landscape of mesophases, emphasizing the interplay between intra-cluster structure and inter-cluster organization. This study provides a systematic framework that could support future investigations of classical thermal melting behavior or quantum phase transitions in similar cluster-forming systems.