Role of hydrogen bonding in charge-ordered organic conductor $α$-(BEDT-TTF)$_2$I$_3$ probed by $^{127}$I nuclear quadrupole resonance
T. Kobayashi, Y. Kato, H. Taniguchi, T. Tsumuraya, K. Hiraki, S. Fujiyama
公開日: 2022/8/11
Abstract
We present $^{127}$I nuclear quadrupole resonance spectra and nuclear relaxation of $\alpha$-(BEDT-TTF)$_2$I$_3$ that undergoes a charge-ordering transition. Only one of the two I$_3$ anion sites shows a significant differentiation in the electric field gradients across the first-order transition. The charge modulation only in the BEDT-TTF layers can not reproduce; instead, an anion-donor interaction accompanied by hydrogen bonding is necessary. The dominating source for the nuclear relaxation is the local libration of the I$_3$ anions, but an anomalous peak is detected just below the transition, as observed by $^{13}$C NMR.