About carrier's self-trapping and dynamical Rashba splitting in the two-dimensional hybrid perovskite (BA)$_2$(MA)$_2$Pb$_3$I$_{10}$
W. Qi, S. Ponzoni, G. Huitric, V. Gorelov, A. Pramanik, Y. Laplace, M. Marsi, E. Papalazarou, S. F. Maehrlein, E. Deleporte, N. Mallik, A. Taleb Ibrahimi, A. Bendounan, K. Zheng, T. Pullerits, L. Perfetti
Published: 2025/8/16
Abstract
Time- and Angle-Resolved Photoelectron Spectroscopy (tr-ARPES) is employed to monitor photoexcited electrons in the two-dimensional hybrid perovskite (BA)$_2$(MA)$_2$Pb$_3$I$_{10}$. Photoelectron intensity maps are in good agreement with ab-initio calculations of the band structure. The effective mass is $-0.18 \pm 0.02 m_e$ and $0.12 \pm 0.02 m_e$ for holes and electrons, respectively. In the photoexcited state, spin-orbit splitting of the conduction band cannot be resolved. This sets the upper bound of photoinduced Rashba coupling to $\alpha_C<2.5$ eV\AA. The correlated electron-hole plasma evolves in Wannier excitons with Bohr radius of 2.5 nm, while no sign of self-trapping in small polarons is found within the investigated time window of up to 120 ps following photoexcitation.