SO2, silicate clouds, but no CH4 detected in a warm Neptune
Achrene Dyrek, Michiel Min, Leen Decin, Jeroen Bouwman, Nicolas Crouzet, Paul Mollière, Pierre-Olivier Lagage, Thomas Konings, Pascal Tremblin, Manuel Gßdel, John Pye, Rens Waters, Thomas Henning, Bart Vandenbussche, Francisco Ardevol Martinez, Ioannis Argyriou, Elsa Ducrot, Linus Heinke, Gwenael Van Looveren, Olivier Absil, David Barrado, Pierre Baudoz, Anthony Boccaletti, Christophe Cossou, Alain Coulais, Billy Edwards, RenÊ Gastaud, Alistair Glasse, Adrian Glauser, Thomas P. Greene, Sarah Kendrew, Oliver Krause, Fred Lahuis, Michael Mueller, Goran Olofsson, Polychronis Patapis, Daniel Rouan, Pierre Royer, Silvia Scheithauer, Ingo Waldmann, Niall Whiteford, Luis Colina, Ewine F. van Dishoeck, Thomas Greve, GÜran Ostlin, Tom P. Ray, Gillian Wright
Published: 2023/11/21
Abstract
WASP-107b is a warm (~740 K) transiting planet with a Neptune-like mass of ~30.5 Earth masses and Jupiter-like radius of ~0.94 Jupiter radius, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO2) was detected in the atmosphere of a hot (~1200 K) Saturn-mass planet from transmission spectroscopy near 4.05 microns, but for temperatures below 1000 K sulphur is predicted to preferably form sulphur allotropes instead of SO2. Here we report the 9-sigma detection of two fundamental vibration bands of SO2, at 7.35 microns and 8.69 microns, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from ~1200 K down to ~740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured (~7-sigma) over simpler cloud setups. Furthermore, water is detected (~12-sigma), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.